Projektnummer

0051788

Zusammenfassung

This project is devoted to the synthesis of a range of novel macrocyclic tetrakisphosphines, in particular polyfunctional and optically active compounds, on the basis of self-assembly processes in three-component systems and the transition metal coordination chemistry of these novel polydentate macrocyclic ligands. An effective method for the synthesis of organophosphorus macrocycles will be developed by employing Mannich-type reactions of secondary bisphosphines with formaldehyde and primary amines (including chiral ones) to give a number of novel 16- to 21-membered macrocycles and c...